Researchers realize photo-driven nitrogen fixation and ammonia synthesis mediated by lithium hydride

Ammonia is essential for food and future energy supply. In the industry, it is mainly produced by the Haber-Bosch process, which operates at high temperatures and pressures. Due to the high energy consumption and carbon emissions of ammonia industry, it is important to develop alternative materials and approaches for efficient N₂ reduction to ammonia driven by renewable energy.

A research group led by Prof. Chen Ping from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS) has realized photo-driven nitrogen fixation and ammonia synthesis mediated by lithium hydride (LiH). The study is published in Nature Chemistry.

LiH is the simplest saline hydride with a band gap of 3.7 eV. It has been investigated for hydrogen storage due to its high hydrogen content (12.5 wt%). However, the dehydrogenation of LiH is thermodynamically unfavorable.

In this study, the researchers found that ultraviolet (UV) illumination of LiH could induce a notable color change from white to light blue, accompanied by the release of a small amount of H₂ under ambient conditions. Such a phenomenon implied that under UV illumination, LiH underwent photolysis resulting in photon-generated electrons trapped in its hydrogen vacancy as long-lived and electron-rich F centers, which showed a fundamentally different mechanism for charge carrier separation.

The researchers indicated that illuminated LiH had an electron-rich surface with hydrogen vacancies, which facilitated the activation of N₂ to form N-H bond. They co-fed a N₂/H₂ mixture with a low H₂ partial pressure into the LiH powders, leading to photo-catalytic ammonia production under ambient conditions.

“This photochemical route is flexible in operation, which may be amenable to the small-scale and distributed ammonia synthesis powered by intermittent solar energy,” said Prof. Chen.