Emergency services were called to the Arundel bypass at about 3pm on Sunday, December 17.
The collision involving a dark grey Peugeot and a silver Mercedes convertible happened on the eastbound carriageway about 100 yards past the junction with Fitzallan Road.
A passenger in the Peugeot, a 53-year-old woman from the Petersfield area in Hampshire, sustained serious injuries and was taken to hospital, where she remains.
The driver of the Peugeot was a 62-year-old man from the Petersfield area and the driver of the Mercedes was a 58-year-old woman from Fontwell.
Sergeant Ian Richardson from the Roads Policing Unit said: “We are investigating the circumstances of the collision and want witnesses or anyone with information to come forward.
“In particular, we would like anyone with dashcam footage of the incident, or of the vehicles in the area in the minutes before the collision, to come forward.”
Information can be reported to Sussex Police online or call 101 and quote serial 638 of 17/12.
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